Yes, you can apply RTI for Copy of the Police Camera Video Recording of Police Control Room (PCR), Madhya Pradesh.
Madhya Pradesh Police operates under direct control of the Department of Home Affairs, Government of Madhya Pradesh and is a "Public Authority" as per Section 2 (h) of the RTI Act 2005 and comes under its ambit.
You can file RTI a Copy of the Video Footage of the PCR from the concerned Police Control Room under Section 2 (f) and Section 2 (i) of the Act. You should mention the date and time of Footage required by you in the Application.
To know more about the procedure to file RTI Applications to Departments in the State of Madhya Pradesh, https://onlinerti.com/how-to-file-rti-online-for-madhyapradesh